Diminishing marginal utility is a cardinal property. In other words: it is not invariant to arbitrary monotonic transformations. This indicates that it cannot be associated with any restriction on preferences (i.e., over a binary relation over consumption), since restrictions on preferences are by nature ordinal.
To see this, consider preferences defined over $\mathbb{R}_{++}$, perhaps thought of as monetary outcomes. If we take $x \succeq y$ if and only if $x \geq y$, we have a convex preference. Notice that both $U(x) = ln(x)$ and $U(x) = e^x$ represent our preference. Both are quasi-concave functions, although only $ln(x)$ is also concave.
If you are willing to entertain additional functional restrictions on $U$, then you can find axiomatic restrictions on $\succeq$ guaranteeing the concavity of $U$ over $\mathbb R$. The obvious example is the expected utility model, which assumes that $U$ is linear over the set of simple lotteries over $\mathbb R$, i.e., takes the form:
$$U(p) = \sum_{supp(p)} p_i u(x_i)$$
where $p$ is a lottery over $\mathbb R$. In this case, the risk aversion axiom---that the certainty equivalent of $p$ is less than the expected value of $p$---will ensure the concavity of $u$.
This is possible only because we have taken a stand on the cardinal normalization of $U$. In other words, any EU representation of $\succeq$ will have a concave $u$ but there still exist other convex non-expected utility representations.