Face value is the value of the item immediately, without regard for the future. For example, the "face value" of a $20 dollar bill is 20 dollars. I remember this because it is, literally, written on the face of the money.
The present value includes a valuation of the future of that money. If I can use that \$20 bill to obtain something else, such as risk-free bonds, then the present value of that $20 bill can be much higher, it might be worth many times that initial face value.
Here's a simple formula showing one of the possible relationships between the two terms:
$$Present \ Value = \Sigma_{t=0}^{\inf} \ FaceValue * i ^ t $$
Where t is the number of periods in the future you are looking, and i is the risk-free bond rate I mentioned already. If you have a sharp eye, you will notice we have assumed that people value all periods (today, tommorrow, etc.) equally. This is probably false, but simplifies things for now. More complex assumptions are available, (and more complex formula!), but the idea remains the same.