The Marshallian demands are functions $x_i(p_1,p_2,m)$.
You treat $m$ as an independent variable rather than $p_1 x_1 + p_2 x_2$.
Since the demands don’t depend on the cross prices (as they don’t appear in the formulas), i.e.,
$\frac{\partial x_1}{\partial p_2} = 0$,
$\frac{\partial x_2}{\partial p_1} = 0$,
they are not complements nor substitute goods, they’re unrelated goods.
Intuitively, if you were to spend all the budget on one good, you would buy
$x_i = \frac{m}{p_i}$ units of that good.
The demands for both goods $x_1, x_2$ look like that multiplied by $\frac{1}{2}$.
This means you’re spending half the budget on each good independently of their relative prices.
For example, let’s say I’m spending half my budget on pizzas and the other half on hamburgers.
If the price of pizzas suddenly increased, I’d still spend that $\frac{m}{2}$ on pizzas, being able to buy less pizzas with it of course.
But I’d still leave the other spending of $\frac{m}{2}$ on hamburgers intact. Since I’m not changing my spending on hamburgers and their price didn’t change, I’d buy the same amount of hamburgers independently of the price change on pizzas.
Note: A beautiful property of the Cobb-Douglas demand function is that when the exponents add up to $1$, each exponent corresponds to the ratio of the budget you’d spend on that specific good.
If the exponents don’t add up to 1, just divide each exponent by the sum of the exponents to get the ratio.
The marshallian demands for a general Cobb-Douglas $u(x_1,x_2) = C x_{1}^{\alpha} x_{2}^{\beta}$ are
$x_1 = \frac{\alpha}{\alpha + \beta} \frac{m}{p_1}$,
$x_2 = \frac{\beta}{\alpha + \beta} \frac{m}{p_2}$.
Therefore, for every Cobb-Douglas utility function, the goods are unrelated (not complements nor substitutes).