For example, considering the allocation between two identical assets with identical mean and variance but independent correlation. Then, the allocated portfolio reduces the variance but keeps the mean the same: the "budget line" is not the line connecting two assets.
In CAPM the set of risky investment opportunities is agiven. This will also include any combinations like the one you propose.
What exactly is a budget line? The budget set is the set of possible solutions in the consumer's utility maximization problem. The budget line is a face of this. Assuming that the consumer's preferences are monotonic, the optimal solution will be somewhere on this line.
The question in CAPM is how to allocate your wealth. In the coordinate system that you gave each investment opportunity is characterized by an expected risk and expected return. You can invest as little or as much as you want to into any of these, thus the question is basically what portion of your wealth to allocate where. The "budget set" is the set of all possible investment opportunities. If we assume that the investor likes higher returns and dislikes higher risk, then we can also say that the optimal choice will be somewhere on the efficient frontier. I think this is as close as you will get to the budget line in this model. (You get further insights if you assume the existence of a risk-free option.)
As Michael Greineker points out, axes matter.
A scooter is shorter and lighter then a truck, while a Rolls-Royce falls inbetween in both dimensions. Possibly there is a scooter and a truck for which
$$
70\% \cdot \text{length}_{\text{scooter}} +
30\% \cdot \text{length}_{\text{truck}}
=
\text{length}_{\text{Rolls-Royce}}
$$
and
$$
70\% \cdot \text{weight}_{\text{scooter}} +
30\% \cdot \text{weight}_{\text{truck}}
=
\text{weight}_{\text{Rolls-Royce}},
$$
thus in this coordinate system the Rolls-Royce will be on a line between the scooter and the truck. Yet this is not a budge line: for approx. \$50,000 I could buy a truck and a scooter, but it would not be enough for a Rolls-Royce.